徐思雯;李振阳;倪生良;孟跃;

• 1:湖州师范学院生命科学学院

摘要(Abstract)：

新制备的Cu(OH)2·yH2O加入到溶有2-甲基苯甲酸、邻菲咯啉的C2H5OH/H2O(1∶1,V/V)混合溶剂中反应,得到一新的铜配合物[Cu(phen)2(C8H7O2)]·(C8H7O2)·4H2O(1)晶体.化合物结构经单晶X-衍射及红外表征,结果表明配合物结晶于三斜晶系,P-1空间群,晶胞参数为:a=10.878(2),b=11.218(2),c=16.178(2),α=72.74(3)°,β=75.54(3)°,γ=78.72(3)°,V=1 809.8(6)3,C40H38N4O8Cu,Mr=766.28,Z=2,Dc=1.406g·cm-3,F(000)=798,最后残余因子R1=0.055 5,wR2=0.133 9.晶体结构中的中心Cu(Ⅱ)原子六配位模式形成畸变的八面体结构,通过分子间O-H…O氢键及芳环$-$堆积作用构筑成超分子框架.

关键词(KeyWords)： 铜配合物;2-甲基苯甲酸配体;结构表征

Abstract:

Keywords:

基金项目(Foundation): supported by 2014 Huzhou University Teaching Reform Project(JGB14025);; the Education Department Project of Zhejiang Province(FX2013136)

作者(Authors): 徐思雯;李振阳;倪生良;孟跃;

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