硬脂酸对磷酸钙包覆氧化铁黄颜料表面的疏水改性研究Hydrophobic Modification of Calcium Phosphate Coated Iron Oxide Yellow Pigments by Stearic Acid
郑明星;徐敏虹;叶方骏;薛丁瑞;虞亮月;李冰欣;吴云峰;
摘要(Abstract):
采用硬脂酸对包覆磷酸钙的氧化铁黄颜料(钙铁黄)表面进行疏水改性.采用红外光谱、XRD等技术对改性前后的钙铁黄进行表征,讨论改性剂用量、改性时间和温度对改性效果的影响.XRD测试结果表明,改性后钙铁黄的晶体结构没有改变.红外光谱分析表明,钙铁黄与硬脂酸之间存在化学吸附.采用活化指数和吸油量评价改性前后钙铁黄的疏水效果,得出最佳的改性条件:硬脂酸用量为钙铁黄质量的5%,改性时间为60 min,改性温度为150℃.此条件下钙铁黄的吸油量为30.06%,活化指数为65%.亲油性实验结果表明,通过硬脂酸改性后,钙铁黄颜料表面由亲水性变为疏水亲油性.
关键词(KeyWords): 氧化铁黄颜料;硬脂酸;表面改性;疏水性
基金项目(Foundation): 浙江省自然科学基金项目(LY19E040001);; 浙江省大学生科技创新活动计划(新苗人才计划)项目(2019R431024)
作者(Authors): 郑明星;徐敏虹;叶方骏;薛丁瑞;虞亮月;李冰欣;吴云峰;
参考文献(References):
- [1] 林治华.氧化铁行业“十二五”回眸及“十三五”展望[J].中国涂料,2016,31(3):47-57.
- [2] HUANG J W,DING Y,LUO X,et al.Solvation effect promoted formation of p-n junction between WO3 and FeOOH:A high performance photoanode for water oxidation[J].Journal of Catalysis,2016,333:200-206.
- [3] ZHANG X,BAI B,LI PG,et al.Novel sea buckthorn biocarbon SBC@beta-FeOOH composites:Efficient removal of doxycycline in aqueous solution in a fixed-bed through synergistic adsorption and heterogeneous Fenton-like reaction[J].Chemical Engineering Journal,2016,284(15):698-707.
- [4] FENG J X,XU H,DONG Y T,et al.FeOOH/Co/FeOOH hybrid nanotube arrays as high-Performance electrocatalysts for the oxygen evolution reaction[J].Angewandte Chemie,2016,128(11):3 758-3 762.
- [5] ZHANG X,WANG X L,WANG Y M,et al.Production of yellow iron oxide pigments by integration of the air oxidation process with bipolar membrane electrodialysis[J].Industrial & Engineering Chemistry Research,2014,53(4):1 580-1 587.
- [6] SNOVSKI R,GRINBLAT J,SOUGRATI M T,et al.Synthesis and characterization of iron,iron oxide and iron carbide nanostructures[J].Journal of Magnetism and Magnetic Materials,2014,349(1):35-44.
- [7] 保积庆,沈筱芳,徐劼,等.化学改性对纳米铁黄粉体表面及其亲油化度的影响研究[J].矿物学报,2015,35(3):293-298.
- [8] LIANG C,WANG B,CHEN J,et al.The effect of acrylamides copolymers on the stability and rheological properties of yellow iron oxide dispersion[J].Colloid Surface A,2017,513(5):136-145.
- [9] HAN Y X,MA X,CAO H,et al.Morphological study and thermal analysis of surface modified α-FeOOH via in situ polymerization of methyl methacrylate[J].Materials Research Bulletin,2004,39(7~8):1 159-1 166.
- [10] GEORGEPODOLSKY.使涂料保持低粘度特性的氧化铁黄颜料[J].中国涂料,1997,12(4):40-41.
- [11] 曾昭仪,裴连娥.透明氧化铁颜料制造工艺[J].涂料工业,1982,12(2):34-37.
- [12] 杨梦霞,索也兵,杜高翔,等.二甲基硅油对中铬黄颜料的表面改性[J].中国粉体技术,2012,18(6):67-70.
- [13] 侯雷,徐如栗,于书尧,等.硬脂酸和硅烷偶联剂KH570对氧化钙疏水改性研究[J].环境科学学报,2016,36(3):960-965.
- [14] 蒋鑫,林仕伟,张苹,等.二氧化钛表面改性及其涂布膜光催化性能的研究[J].人工晶体学报,2017,46(4):668-674.
- [15] 刘光,未碧贵,武福平,等.石英砂滤料表面干法改性制备疏水性除油滤料[J].化工学报,2016,5(5):2 101-2 108.
- [16] HONG R Y,PAN T T,QIAN J Z,et al.Synthesis and surface modification of ZnO nanoparticles [J].Chem Eng J,2006,119(23):71-8l.
- [17] 潘国祥,盛欧微,陈健,等.通过包覆含铝物质提高氧化铁黄颜料的耐热性能[J].硅酸盐学报,2016,44(2):308-313.
- [18] LI Z B,CAO M J,CHEN L M,et al.Stearic acid-modified γ-Al2O3 particles for dispersion properties[M]//Advanced Graphic Communications,Packaging Technology and Materials.Singapore:Springer Singapore,2015:903-909.
- [19] 方泽,黄倩,许凯波,等.十八烷基三甲基氯化铵改性氧化铁黄的分散性能研究[J].湖州师范学院学报,2019,41(8):49-53.